Metals and Equilibria: Dynamic Equilibrium
Metals and Equilibria: Dynamic Equilibrium
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Dynamic equilibrium is a state reached in a reversible reaction where the forward and reverse reactions take place at the same rate. Therefore, the concentration of the reactants and products does not change over time.
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Understand that equilibrium is possible only in a closed system where no reactants or products can escape or be added.
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A reversible reaction is indicated by the use of forward and reverse arrows instead of the usual one-way arrow.
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The equilibrium symbol is used (double arrow: ⇌) to indicate that a reaction can proceed in both the forward and reverse directions.
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In terms of chemical equations, a reversible reaction could be represented as A + B ⇌ C + D.
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Learning the concept of Le Chatelier’s principle, which states that if a dynamic equilibrium is disrupted by changing the conditions, the position of equilibrium moves to counteract the change, is also necessary.
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For instance, if the concentration of a reactant is increased, the equilibrium will shift to decrease it (making more product). Conversely, decreasing the concentration of a product or increasing the temperature (for an endothermic reaction) will shift the equilibrium to make more of that product.
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Also, note that changing the temperature or pressure will have an impact on the equilibrium of a reaction. For high pressure, the reaction will favour the side with fewer gaseous molecules and for high temperature, it will favour the endothermic reaction.
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It’s essential to familiarise yourself with diagrams and graphs that represent the changes in concentration over time in a reversible reaction to understand the concept of dynamic equilibrium.
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Revisit and understand examples of real-world scenarios where dynamic equilibrium is crucial, such as the Haber-Bosch process for ammonia synthesis or the production of methanol, as these are often used in questions.