Preparation of Salts

Preparation of Salts

Preparation of Soluble Salts

  • Any soluble salt can be made by reacting a suitable insoluble base (such as a metal oxide, metal hydroxide or metal carbonate) with an acid.
  • Alternatively, a salt can also be made by neutralising a solution of an acid by adding an alkali to it (such as a soluble hydroxide or carbonate).
  • A chemical reaction usually occurs, producing the salt and water.
  • The type of acid used will determine the non-metal part of the salt’s name, for example, sulfuric acid will produce a sulfate salt, hydrochloric acid a chloride salt and nitric acid a nitrate salt.

Preparation of Insoluble Salts

  • Insoluble salts are made by mixing two solutions to form a precipitate.
  • This is often done by mixing solutions of two soluble salts.
  • This process is known as precipitation.
  • The resulting mixture can then be filtered to obtain the precipitate.

Specific Salts

  • Copper sulfate: This blue salt can be made by reacting copper oxide or copper carbonate with sulfuric acid.
  • Sodium chloride: This common salt can be made by neutralising hydrochloric acid with sodium hydroxide solution.
  • Iron(III) oxide: This red-brown solid can be made by precipitating iron(III) sulfate solution with sodium hydroxide solution.
  • Barium sulfate: This white solid is made by precipitating barium chloride solution with sulfuric acid.

Note: Reacting solutions of barium chloride and sodium sulfate will also produce insoluble barium sulfate, and this is a good way to test for sulfate ions in a solution. If a white precipitate forms when barium chloride solution is added to a solution, the original solution likely contains sulfate ions.

Important Safety Considerations

  • Always wear protective eyewear and gloves when handling acids and alkalis.
  • Never add water to acid, always add—carefully—acid to water.
  • Dispose of acids, alkalis, and neutralisation products according to safe disposal procedures.