Nitrogen and Ammonia

Nitrogen and Ammonia

Nitrogen and Its Properties

  • Nitrogen is a gas that exists as diatomic molecules (N2) and makes up about 78% of the Earth’s atmosphere.
  • It is a nonmetal with symbol N and atomic number 7.
  • Nitrogen is colourless, odourless and tasteless.
  • At room temperature, it behaves as an inert gas due to the strong triple bond in its diatomic molecule, making it relatively unreactive.

Nitrogen Cycle

  • The Nitrogen Cycle is a biogeochemical process through which nitrogen is converted into multiple chemical forms as it circulates in the environment.
  • The process primarily includes nitrogen fixation, ammonification, nitrification, and denitrification.
  • Nitrogen is essential for many biological processes; including the production of proteins and DNA.

Ammonia and the Haber Process

  • Ammonia (NH3) is a useful compound of nitrogen, extensively used in agriculture as a fertilizer due to its high nitrogen content.
  • Ammonia is produced industrially by the Haber Process which combines nitrogen from the air with hydrogen obtained from natural gas in presence of an iron catalyst.
  • The equation for the Haber process is: N2(g) + 3H2(g) ↔ 2NH3(g)
  • This reaction is reversible, operated under conditions of high pressure (200 atm) and a temperature of about 450°C to shift the equilibrium to the right and maximise yield.

Impact of Ammonia on Environment

  • While ammonia is valuable in the production of fertilisers, its use also has environmental implications.
  • Excess usage can lead to eutrophication, a process where water bodies become overly enriched with nutrients, resulting in the excessive growth of algae and other aquatic plants.
  • This can disrupt normal water systems, leading to a decrease in water oxygen levels and harming aquatic life.

Ammonia Safety Measures

  • Ammonia vapour can be irritating and harmful to the eyes and respiratory system.
  • In case of exposure, it’s essential to flush the eyes and skin with plenty of water, and seek medical attention if necessary.
  • Handling and transportation of ammonia require strict safety measures including the use of personal protective equipment.