Nitrogen and Ammonia
Nitrogen and Ammonia
Nitrogen and Its Properties
- Nitrogen is a gas that exists as diatomic molecules (N2) and makes up about 78% of the Earth’s atmosphere.
- It is a nonmetal with symbol N and atomic number 7.
- Nitrogen is colourless, odourless and tasteless.
- At room temperature, it behaves as an inert gas due to the strong triple bond in its diatomic molecule, making it relatively unreactive.
Nitrogen Cycle
- The Nitrogen Cycle is a biogeochemical process through which nitrogen is converted into multiple chemical forms as it circulates in the environment.
- The process primarily includes nitrogen fixation, ammonification, nitrification, and denitrification.
- Nitrogen is essential for many biological processes; including the production of proteins and DNA.
Ammonia and the Haber Process
- Ammonia (NH3) is a useful compound of nitrogen, extensively used in agriculture as a fertilizer due to its high nitrogen content.
- Ammonia is produced industrially by the Haber Process which combines nitrogen from the air with hydrogen obtained from natural gas in presence of an iron catalyst.
- The equation for the Haber process is: N2(g) + 3H2(g) ↔ 2NH3(g)
- This reaction is reversible, operated under conditions of high pressure (200 atm) and a temperature of about 450°C to shift the equilibrium to the right and maximise yield.
Impact of Ammonia on Environment
- While ammonia is valuable in the production of fertilisers, its use also has environmental implications.
- Excess usage can lead to eutrophication, a process where water bodies become overly enriched with nutrients, resulting in the excessive growth of algae and other aquatic plants.
- This can disrupt normal water systems, leading to a decrease in water oxygen levels and harming aquatic life.
Ammonia Safety Measures
- Ammonia vapour can be irritating and harmful to the eyes and respiratory system.
- In case of exposure, it’s essential to flush the eyes and skin with plenty of water, and seek medical attention if necessary.
- Handling and transportation of ammonia require strict safety measures including the use of personal protective equipment.