Non-Metals and Their Compounds

Non-Metals and Their Compounds

Non-Metals

  • Non-metals are elements that typically do not have the physical and chemical properties of metals.
  • Non-metals can be gases, liquids, or solids at room temperature, and are usually poor conductors of heat and electricity.
  • Some non-metals, such as carbon, sulphur, phosphorus, and the halogens are good reaction partners for most metals and have a more diverse range of chemical behaviour than metals.
  • Oxygen is a very reactive non-metal and is widely distributed in nature. It forms oxides with both metals and non-metals.

The Halogens

  • The group of non-metals known as the halogens includes fluorine, chlorine, bromine, iodine and astatine.
  • Halogens exist as diatomic molecules (two atoms per molecule) in their elemental form, e.g. Cl2, Br2, I2.
  • They are highly reactive, especially with alkali metals and alkaline earth metals, forming salts such as sodium chloride (table salt).

Oxides of Non-Metals

  • Non-metal oxides react with water to form acidic solutions. For example, sulphur dioxide (SO2) reacts with water to produce sulphurous acid (H2SO3).
  • Some non-metal oxides are considered to be pollutants. These include carbon dioxide (CO2), a greenhouse gas which contributes to global warming, and sulphur dioxide (SO2), which can lead to acid rain.

Compounds of Non-Metals

  • Non-metals can bond with other non-metals to form covalent compounds. An important example is water (H2O), which is a compound of the non-metals hydrogen and oxygen.
  • Non-metal elements like nitrogen, phosphorus, oxygen, and sulphur are vital for life on earth. They form part of many key biological molecules, including amino acids, nucleic acids, and ATP.
  • Carbon is another highly important non-metal. It is the primary component of organic compounds, which form the basis of all life on earth. Carbon also forms different allotropes including diamond and graphite.

Environmental Impact

  • Non-metals and their compounds have a significant impact on the environment.
  • Carbon dioxide and methane (a compound of carbon and hydrogen) are significant greenhouse gases contributing to climate change.
  • Nitrogen oxides and sulphur oxides contribute to air pollution and acid rain, which can damage ecosystems.
  • Several non-metal compounds are used as fertilisers (such as ammonium nitrate) but their overuse can lead to eutrophication, posing a threat to aquatic life.

Physical Properties

  • Non-metals are typically not shiny in appearance.
  • They usually have lower melting and boiling points than metals.
  • They tend to be brittle (easy to break) when solid.
  • Non-metals are typically less dense than metals.
  • Non-metals do not have free electrons and thus are bad conductors of electricity and heat.

Chemical Properties

  • Non-metals react by gaining electrons to obtain a stable electronic configuration.
  • They form negative ions (anions).
  • Non-metals react with metals to form ionic compounds.
  • They can also react with other non-metals to form covalent compounds.
  • Non-metals are generally more volatile (turn into gases) than metals.
  • They have relatively large atomic sizes compared to metals.
  • Non-metals have higher electronegativity and ionisation energy than metals.