Group 1 (Alkali Metals)

Group 1 (Alkali Metals)

General Characteristics

  • Alkali metals are found in Group 1 of the periodic table.
  • They include lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), and francium (Fr).
  • These metals are characterised by their soft, silvery appearance, and they are highly reactive.
  • Being in the same group, they share similar properties and similar reactivity patterns due to the structure of their outer electron shell.
  • Alkali metals are stored in oil, as they react violently with both water and oxygen from the air.

Physical Properties

  • Alkali metals increase in reactivity down the group.
  • They have low melting and boiling points, which decrease down the group.
  • They are soft and can be easily cut with a knife.
  • Alkali metals are low density; lithium, sodium and potassium are less dense than water.

Chemical Properties

  • Alkali metals have one electron on their outer shell, which is why they are incredibly reactive.
  • They will willingly donate this outer electron in chemical reactions.
  • Alkali metals react violently with water, producing hydrogen gas and alkaline solutions.
  • When alkali metals react with oxygen, they form metal oxides. More reactive alkali metals can form peroxides or superoxides.
  • Alkali metals also react with chlorine, forming metal chlorides.

Specific Reactions

  • Reaction with Water: Alkali Metals + Water -> Alkali Metal Hydroxide + Hydrogen
  • Reaction with Oxygen: 4 Alkali Metals + O2 -> 2 Alkali Metal Oxides
  • Reaction with Chlorine: 2 Alkali Metals + Cl2 -> 2 Alkali Metal Chlorides

Hazards and Precautions

  • Due to their reactivity, alkali metals are typically handled with caution in the lab.
  • It’s necessary to avoid exposing alkali metals to air or moisture; they are stored in air-tight containers filled with inert oil.
  • When reacting alkali metals with water or halogens, ensure the setup is designed to contain any explosive reactions.