Group 1 (Alkali Metals)
Group 1 (Alkali Metals)
General Characteristics
- Alkali metals are found in Group 1 of the periodic table.
- They include lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), and francium (Fr).
- These metals are characterised by their soft, silvery appearance, and they are highly reactive.
- Being in the same group, they share similar properties and similar reactivity patterns due to the structure of their outer electron shell.
- Alkali metals are stored in oil, as they react violently with both water and oxygen from the air.
Physical Properties
- Alkali metals increase in reactivity down the group.
- They have low melting and boiling points, which decrease down the group.
- They are soft and can be easily cut with a knife.
- Alkali metals are low density; lithium, sodium and potassium are less dense than water.
Chemical Properties
- Alkali metals have one electron on their outer shell, which is why they are incredibly reactive.
- They will willingly donate this outer electron in chemical reactions.
- Alkali metals react violently with water, producing hydrogen gas and alkaline solutions.
- When alkali metals react with oxygen, they form metal oxides. More reactive alkali metals can form peroxides or superoxides.
- Alkali metals also react with chlorine, forming metal chlorides.
Specific Reactions
- Reaction with Water: Alkali Metals + Water -> Alkali Metal Hydroxide + Hydrogen
- Reaction with Oxygen: 4 Alkali Metals + O2 -> 2 Alkali Metal Oxides
- Reaction with Chlorine: 2 Alkali Metals + Cl2 -> 2 Alkali Metal Chlorides
Hazards and Precautions
- Due to their reactivity, alkali metals are typically handled with caution in the lab.
- It’s necessary to avoid exposing alkali metals to air or moisture; they are stored in air-tight containers filled with inert oil.
- When reacting alkali metals with water or halogens, ensure the setup is designed to contain any explosive reactions.