Chemical Formulae, Equations and Calculations

Chemical Formulae, Equations and Calculations

Chemical Formulae

  • A chemical formula represents the types and numbers of atoms in the smallest unit of a substance.
  • The elements in a compound are represented by their chemical symbols, as found in the periodic table.
  • Subscript numbers are used to indicate the number of atoms of each element in a compound.
  • For example, Water is represented as H₂O, where 2 is the subscript representing two hydrogen (H) atoms bonded with one oxygen (O) atom.

Chemical Equations

  • A chemical equation represents a chemical reaction using the chemical formulas of the reactants and products.
  • Reactants are the substances that are changed in the reaction, and are written on the left of the equation.
  • Products are the substances that are produced in the reaction, and are written on the right of the equation.
  • The two sides of the equation are separated by an arrow (→) that signifies the direction of the reaction.
  • For example, the reaction of hydrogen with oxygen to form water is represented as: 2H₂ + O₂ → 2H₂O.

Balancing Chemical Equations

  • In a balanced chemical equation, the number of atoms for each element is the same on the reactant side as on the product side, demonstrating the law of conservation of mass.
  • To balance an equation, numbers called coefficients are placed in front of the chemical formulas in the equation, altered until each type of atom is balanced.

Moles and Calculations

  • The mole is the unit used to count entities at the atomic and molecular scale.
  • One mole of any substance contains Avogadro’s number (6.022 × 10²³) of entities (atoms, molecules, ions, etc.).
  • The molar mass of a substance is the mass in grams that one mole of that substance would have. It is numerically equal to the substance’s relative atomic or molecular weight.
  • Stoichiometry involves the calculation of quantities in chemical equations.
  • By using the coefficients in a balanced chemical equation, you can predict the amount of product that will be formed and the amount of reactant needed.

Limiting Reactant and Yield Calculations

  • The limiting reactant is the reactant that is completely used up in a reaction and determines the maximum amount of product that can be formed.
  • The yield of a reaction refers to the amount of product obtained.
  • Theoretical yield is the maximum amount of product that could be formed from the reactant amounts.
  • Actual yield is the amount of product actually obtained, which is often less than the theoretical yield due to side reactions or incomplete reactions.
  • The percentage yield is calculated by (actual yield / theoretical yield) * 100% and represents the efficiency of a reaction.