Group 7 (Halogens)

Group 7 (Halogens)

General Characteristics

  • Halogens are found in Group 7 of the periodic table.
  • This group includes fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and astatine (At).
  • They exist as diatomic molecules, meaning they’re made up of two atoms.
  • Halogens are non-metals with coloured vapours.
  • Their reactivity decreases as you move down the group.
  • The various halogens have distinct physical states at room temperature, with fluorine and chlorine as gases, bromine as a liquid and iodine and astatine as solids.

Physical Properties

  • Halogens decrease in reactivity down the group.
  • They have increasing melting and boiling points moving down the group.
  • The various states (gas, liquid, solid) of halogens at room temperature offers a direct reflection of these increasing boiling points.
  • Halogens generally have a high electron affinity or a strong attraction to electrons.

Chemical Properties

  • Halogens have seven electrons in their outer shell, hence their name which means “salt-forming”.
  • They are extremely reactive, particularly with alkali metals and hydrogen.
  • In reactions, halogens gain an electron to achieve a stable electron configuration.
  • These reactions usually lead to the formation of salts.

Specific Reactions

  • Reaction with Alkali Metals: Halogen + Alkali Metal -> Salt
  • Reaction with Hydrogen: H2 + Halogen -> Hydrogen Halide (a type of salt)

Hazards and Precactions

  • Halogens are toxic and can be hazardous to health; for precaution, many are stored in sealed containers.
  • Bromine is especially dangerous; it’s a corrosive, toxic liquid which gives off poisonous fumes.
  • Iodine is less dangerous, but it sublimates to produce a purple vapour which is harmful in large quantities.
  • Always ensure good ventilation when working with halogens, and try to avoid inhalation or skin contact.