Group 7 (Halogens)
Group 7 (Halogens)
General Characteristics
- Halogens are found in Group 7 of the periodic table.
- This group includes fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and astatine (At).
- They exist as diatomic molecules, meaning they’re made up of two atoms.
- Halogens are non-metals with coloured vapours.
- Their reactivity decreases as you move down the group.
- The various halogens have distinct physical states at room temperature, with fluorine and chlorine as gases, bromine as a liquid and iodine and astatine as solids.
Physical Properties
- Halogens decrease in reactivity down the group.
- They have increasing melting and boiling points moving down the group.
- The various states (gas, liquid, solid) of halogens at room temperature offers a direct reflection of these increasing boiling points.
- Halogens generally have a high electron affinity or a strong attraction to electrons.
Chemical Properties
- Halogens have seven electrons in their outer shell, hence their name which means “salt-forming”.
- They are extremely reactive, particularly with alkali metals and hydrogen.
- In reactions, halogens gain an electron to achieve a stable electron configuration.
- These reactions usually lead to the formation of salts.
Specific Reactions
- Reaction with Alkali Metals: Halogen + Alkali Metal -> Salt
- Reaction with Hydrogen: H2 + Halogen -> Hydrogen Halide (a type of salt)
Hazards and Precactions
- Halogens are toxic and can be hazardous to health; for precaution, many are stored in sealed containers.
- Bromine is especially dangerous; it’s a corrosive, toxic liquid which gives off poisonous fumes.
- Iodine is less dangerous, but it sublimates to produce a purple vapour which is harmful in large quantities.
- Always ensure good ventilation when working with halogens, and try to avoid inhalation or skin contact.