Inorganic Chemistry: The Periodic Table

Inorganic Chemistry: The Periodic Table

Understanding the Periodic Table

  • The Periodic Table is a systematic arrangement of elements, organised based on their atomic number, electron configuration, and recurring chemical properties.
  • Elements in the same group (vertical column) have similar chemical and physical properties since they have the same number of valence electrons.
  • Elements in the same period (horizontal row) have their outermost electrons in the same shell level.
  • Atomic number, denoted by ‘Z’, represents the number of protons in an atom. It is unique to each element and increases in a regular manner across the periods of the periodic table.

Periodicity

  • Periodicity refers to the recurring trends in physical and chemical properties of elements across periods or groups on the periodic table.
  • For example, ionization energy, the energy required to remove an electron from an atom, generally increases across a period from left to right and decreases down a group.
  • Another example is electron affinity, the energy released when an electron is added to an atom, which also generally increases across a period but decreases down a group.

Transition Metals

  • Transition metals are elements found in groups 3-12 of the periodic table, possessing high melting points, high densities, and the ability to form coloured compounds.
  • These metals are noted for their variable oxidation states and their ability to form complex ions.
  • Common examples of transition metals include iron, copper, and nickel.

Noble Gases

  • Noble gases, consisting of helium, neon, argon, krypton, xenon, and radon, have full electron shells and are found in Group 18.
  • These gases are colourless, odourless, and tasteless, and are renowned for their low reactivity due to their stable electron configurations.
  • They have several uses, including filling balloons (helium), providing the glow in neon lights (neon), and being used in medical imaging (xenon).

Alkali Metals and Alkaline Earth Metals

  • Alkali metals (Group 1) and alkaline earth metals (Group 2) are highly reactive metals, with alkali metals being more reactive than alkaline earth metals.
  • Alkali metals only have one electron in their outermost energy level, leading to a strong tendency to lose this electron, while alkaline earth metals have two electrons in their outermost energy level.
  • Alkali metals react vigorously with water, while alkaline earth metals react less vigorously.

Halogens

  • Halogens (Group 17) are non-metals that need one more electron to attain a stable noble gas configuration, leading them to be very reactive.
  • As you move down the group, the reactivity decreases - for example, Fluorine is the most reactive, while Iodine is much less so.
  • Halogens exist as diatomic molecules in their natural state (e.g., Cl2, Br2) and they display a range of physical states at room temperature (e.g., gas (Fluorine, Chlorine), liquid (Bromine), solid(Iodine, Astatine)).

Predicting Chemical Properties

  • The periodic table can be used to predict the chemical properties of an element based on its position.
  • For example, elements in the same group will tend to form ions with the same charge, and elements in the same period will have the same number of electron shells.
  • Additionally, elements on the left of the periodic table (metals) will typically lose electrons to form positive ions, while those on the right (non-metals) will typically gain electrons to form negative ions.