Group 1 and 2 Compounds
Group 1 and 2 Compounds
Group 1 (Alkali Metals) and Group 2 (Alkaline Earth Metals) Compounds:
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Group 1 metals react readily with non-metals to form ionic compounds.
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Alkali metals react with oxygen to form oxides, with hydrogen to form hydrides, and with halogens to form halides.
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Lithium, from Group 1, forms Li2O, a simple oxide, while sodium forms Na2O2, a peroxide, and the other Group 1 metals form superoxides (KO2, RbO2, CsO2).
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The solubility and reactivity of Group 2 metal compounds increase down the group due to the decrease in ionisation energy.
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Group 2 metals react with water to a different extent: Mg does not react with cold water but with boiling water or steam, while Ba reacts readily with cold water.
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Alkaline Earth Metal oxides and hydroxides are bases, and their reactivity increases down the group. They react with water to form alkaline solutions.
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The trend in melting points and boiling points in Group 1 and Group 2 elements is due to the strength of metallic bonding, which itself depends on the charge on the ion and the size of the ion.
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Trend in first ionisation energy down groups 1 and 2: decreases because the atomic radius increases, the nuclear charge increases and the electron shielding increases.
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Hydrogen is not a member of Group 1 although it is located above lithium in the Periodic table. It only has one electron in its outermost shell and its chemistry is markedly different from alkali metals.
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Group 1 and 2 metals and their compounds are often used in the industry. For instance, Group 1 compounds are used in various applications from table salt (NaCl) to lithium batteries. Group 2 metal compounds have applications ranging from cement (calcium oxide) to stomach antacids (magnesium hydroxide).