Group 1 and 2 Compounds

Group 1 and 2 Compounds

Group 1 (Alkali Metals) and Group 2 (Alkaline Earth Metals) Compounds:

  • Group 1 metals react readily with non-metals to form ionic compounds.

  • Alkali metals react with oxygen to form oxides, with hydrogen to form hydrides, and with halogens to form halides.

  • Lithium, from Group 1, forms Li2O, a simple oxide, while sodium forms Na2O2, a peroxide, and the other Group 1 metals form superoxides (KO2, RbO2, CsO2).

  • The solubility and reactivity of Group 2 metal compounds increase down the group due to the decrease in ionisation energy.

  • Group 2 metals react with water to a different extent: Mg does not react with cold water but with boiling water or steam, while Ba reacts readily with cold water.

  • Alkaline Earth Metal oxides and hydroxides are bases, and their reactivity increases down the group. They react with water to form alkaline solutions.

  • The trend in melting points and boiling points in Group 1 and Group 2 elements is due to the strength of metallic bonding, which itself depends on the charge on the ion and the size of the ion.

  • Trend in first ionisation energy down groups 1 and 2: decreases because the atomic radius increases, the nuclear charge increases and the electron shielding increases.

  • Hydrogen is not a member of Group 1 although it is located above lithium in the Periodic table. It only has one electron in its outermost shell and its chemistry is markedly different from alkali metals.

  • Group 1 and 2 metals and their compounds are often used in the industry. For instance, Group 1 compounds are used in various applications from table salt (NaCl) to lithium batteries. Group 2 metal compounds have applications ranging from cement (calcium oxide) to stomach antacids (magnesium hydroxide).