Collision Model

Collision Model

  • The Collision Model describes the process of how reactions take place.
  • It states that for a reaction to occur, reactant particles (atoms, molecules, or ions) must collide with each other with enough force and in the correct orientation.
  • A successful collision that leads to a chemical reaction is termed an effective collision.

Factors Influencing Collision Frequency

  • Concentration: When the concentration of reactants is increased, the likelihood of collisions happening is also increased, thus speeding up the reaction rate.
  • Surface Area: By increasing the surface area of a reactant, more particles are exposed for collisions, leading to an increased reaction rate.
  • Pressure: Increasing pressure (in reactions involving gases) effectively increases the concentration, leading to more frequent collisions and a faster reaction rate.

Activation Energy and The Collision Model

  • Not every collision results in a reaction. The particles must collide with a certain minimum energy called the activation energy (Ea).
  • Activation energy is the minimum energy that needs to be surpassed during a collision for a reaction to take place.
  • If the energy of the colliding particles is less than the activation energy, they will simply bounce off each other without reacting.

Temperature and The Collision Model

  • Temperature influences the reaction rate by affecting both the frequency and the energy of the collisions.
  • Higher temperatures increase the kinetic energy of the particles, leading to more collisions as well as giving more particles the requisite activation energy for effective collisions.

Reaction Mechanisms

  • Many complex reactions take place in stages, with each stage involving a different, simpler reaction. Each of these stages is called an elementary step.
  • The sequence of elementary steps that make up the overall reaction is called the reaction mechanism.
  • Some elementary steps involve the collision and reaction of two particles, known as bimolecular steps, while others involve just one, known as unimolecular steps.