Types of Chemical Bonds

Types of Chemical Bonds

Covalent bonding

  • Covalent bonding occurs when atoms share one or more pairs of electrons. This generally happens between non-metals.

  • A simple example is a molecule of oxygen (O2), where each oxygen atom shares two electrons with the other, forming a double bond.

  • If only one pair of electrons is shared, it’s a single bond (as in H2). If three pairs are shared, it’s a triple bond (as in N2).

  • In a covalently-bonded molecule, the shared electrons are attracted towards both nuclei, which helps to hold the atoms together.

  • Water (H2O), methane (CH4), and carbon dioxide (CO2) are examples of molecules with covalent bonds.

Ionic bonding

  • Ionic bonding involves the transfer of electrons from one atom to another. This generally happens between metals and non-metals.

  • A metal atom can lose an electron (or more) to a non-metal atom, creating a positively-charged cation and a negatively-charged anion.

  • These oppositely-charged ions attract each other due to electrostatic forces, forming ionic bonds.

  • Sodium chloride (NaCl) is a classic example of an ionic compound. Sodium loses an electron and becomes a Na+ cation, whereas chlorine gains an electron to become a Cl- anion.

Metallic bonding

  • Metallic bonding occurs in metals, where electrons are shared amongst a lattice of positive ions.

  • These free electrons form a ‘sea of electrons’ that can move freely around the metal lattice, leading to properties such as good electrical conductivity and malleability.

  • Classic examples of metallic bonding are pure metals like iron (Fe), copper (Cu), and aluminium (Al).

Hydrogen bonding

  • Hydrogen bonding is a type of dipole-dipole interaction that occurs when a hydrogen atom bonded to a highly electronegative atom (e.g. oxygen, nitrogen or fluorine) is attracted to another electronegative atom in a different molecule.

  • Although weaker than ionic or covalent bonds, hydrogen bonds are significantly stronger than other types of intermolecular forces.

  • Hydrogen bonding is responsible for many of water’s unique properties, including its relatively high boiling point and its ability to dissolve many substances.

London dispersion forces

  • London dispersion forces are weak intermolecular forces that exist between all atoms and molecules.

  • They arise due to temporary fluctuations in the electron distribution, which create instantaneous dipoles that induce dipoles in neighbouring atoms or molecules.

  • The strength of London dispersion forces increases with the size and complexity of the atoms or molecules involved, but they are generally much weaker than other types of bonding.