Types of Chemical Bonds
Types of Chemical Bonds
Covalent bonding
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Covalent bonding occurs when atoms share one or more pairs of electrons. This generally happens between non-metals.
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A simple example is a molecule of oxygen (O2), where each oxygen atom shares two electrons with the other, forming a double bond.
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If only one pair of electrons is shared, it’s a single bond (as in H2). If three pairs are shared, it’s a triple bond (as in N2).
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In a covalently-bonded molecule, the shared electrons are attracted towards both nuclei, which helps to hold the atoms together.
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Water (H2O), methane (CH4), and carbon dioxide (CO2) are examples of molecules with covalent bonds.
Ionic bonding
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Ionic bonding involves the transfer of electrons from one atom to another. This generally happens between metals and non-metals.
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A metal atom can lose an electron (or more) to a non-metal atom, creating a positively-charged cation and a negatively-charged anion.
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These oppositely-charged ions attract each other due to electrostatic forces, forming ionic bonds.
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Sodium chloride (NaCl) is a classic example of an ionic compound. Sodium loses an electron and becomes a Na+ cation, whereas chlorine gains an electron to become a Cl- anion.
Metallic bonding
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Metallic bonding occurs in metals, where electrons are shared amongst a lattice of positive ions.
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These free electrons form a ‘sea of electrons’ that can move freely around the metal lattice, leading to properties such as good electrical conductivity and malleability.
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Classic examples of metallic bonding are pure metals like iron (Fe), copper (Cu), and aluminium (Al).
Hydrogen bonding
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Hydrogen bonding is a type of dipole-dipole interaction that occurs when a hydrogen atom bonded to a highly electronegative atom (e.g. oxygen, nitrogen or fluorine) is attracted to another electronegative atom in a different molecule.
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Although weaker than ionic or covalent bonds, hydrogen bonds are significantly stronger than other types of intermolecular forces.
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Hydrogen bonding is responsible for many of water’s unique properties, including its relatively high boiling point and its ability to dissolve many substances.
London dispersion forces
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London dispersion forces are weak intermolecular forces that exist between all atoms and molecules.
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They arise due to temporary fluctuations in the electron distribution, which create instantaneous dipoles that induce dipoles in neighbouring atoms or molecules.
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The strength of London dispersion forces increases with the size and complexity of the atoms or molecules involved, but they are generally much weaker than other types of bonding.