Alkenes
Overview of Alkenes
- Alkenes are a category of hydrocarbons that contain at least one carbon-carbon double bond.
- These double bonds make alkenes unsaturated hydrocarbons.
- The general formula for alkenes is CnH2n where ‘n’ is the number of carbon atoms.
Properties of Alkenes
- The double bonds in alkenes give them greater reactivity than their alkane counterparts.
- They are non-polar compounds and hence insoluble in water but soluble in organic solvents.
- Like alkanes, as the length of the carbon chain increases, so does the boiling point of alkenes.
Nomenclature of Alkenes
- The names of alkenes, similar to those of alkanes, start with a prefix denoting the number of carbon atoms (‘meth-’ for 1, ‘eth-’ for 2, ‘prop-’ for 3, and so forth).
- This prefix is followed by the suffix ‘-ene’ to denote the presence of a carbon-carbon double bond.
- If more than one double bond exists, the suffix changes to denote the number (‘-diene’ for two, ‘-triene’ for three, and so forth).
Isomerism in Alkenes
- More structural isomerism potential exists in alkenes than alkanes due to the presence of double bonds.
- They can exhibit both chain isomerism and position isomerism.
- Alkenes with more than one double bond can display geometric isomerism.
Reactions of Alkenes
- Alkenes can partake in addition reactions due to the presence of double bonds.
- A common example of this is the reaction with bromine water, which decolourises in the presence of an alkene.
- They can also undergo hydrogenation (addition of hydrogen in the presence of a catalyst) to become alkanes.
- Alkenes also undergo combustion, burning in oxygen to produce carbon dioxide and water. However, incomplete combustion can produce carbon (soot) or carbon monoxide.