Organic Chemistry
Organic Chemistry Basics
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Organic Chemistry is the study of carbon-containing compounds, including hydrocarbons and their derivatives.
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Carbon has four valence electrons, enabling it to form covalent bonds with other elements. These bonds can result in different structures like chains, branches and rings.
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Hydrocarbons are organic compounds composed of hydrogen and carbon atoms. They’re mainly divided into alkanes, alkenes, and alkynes based on their bonding.
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Isomers are compounds with the same molecular formula but different structural formulas.
Alkanes
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Alkanes have only single bonds between the carbon atoms and follow the general formula CnH2n+2.
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These are saturated compounds as they contain as many hydrogen atoms as possible.
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They exhibit chain isomerism where the carbon atoms can be rearranged in different ways.
Alkenes and Alkynes
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Alkenes have one or more carbon-carbon double bonds and follow the general formula CnH2n.
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Alkynes have one or more carbon-carbon triple bonds and follow the general formula CnH2n-2.
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Both alkenes and alkynes are unsaturated hydrocarbons as they contain fewer hydrogen atoms than alkanes.
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They engage in addition reactions where the double or triple bond breaks to allow new elements to bond with the carbon atoms.
Organic Reactions
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Combustion is a reaction of hydrocarbons with oxygen to produce carbon dioxide and water. Incomplete combustion results in carbon (soot) or carbon monoxide.
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Substitution reactions are characteristic for alkanes where one or more hydrogen atoms are replaced with another atom or group.
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Addition reactions are characteristic for alkenes and alkynes, where atoms are added to the carbon-carbon double or triple bonds.
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Esterification is a reaction between carboxylic acids and alcohols to form an ester and water.
Functional Groups
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Functional groups determine the reactivity and polarity of organic compounds.
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Examples of functional groups are alcohol (-OH), carboxylic acid (-COOH), aldehyde (-CHO), ketone (-CO-), halide (-X), and amines (-NH2).
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The presence of functional groups allows for a wide range of chemical reactions.
Polymers
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Polymers are large molecules made up of repeating subunits called monomers.
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Addition polymers are formed from alkenes through an addition reaction.
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Condensation polymers are formed when two different monomers combine, releasing a small molecule like water.
Crude Oil and Fuels
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Crude oil is a mixture of various hydrocarbons. It’s processed through a method called fractional distillation to produce useful products like petrol, diesel, jet fuel, and gases.
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Fossil fuels release carbon dioxide when burnt, contributing to global warming, making the search for renewable energy sources vital.