The Periodic Table: Group 7

The Periodic Table: Group 7

  • Group 7 of the Periodic Table, better known as the Halogens, includes fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and astatine (At).
  • Halogens have seven electrons in their outer shell. This means they are very reactive as they strive to gain that extra electron to achieve a stable full outer shell.
  • The reactivity of halogens decreases as you move down the group. Fluorine is the most reactive halogen, while astatine, usually the last halogen listed in textbooks, is the least reactive.
  • Halogens are highly reactive non-metals. They can form salts with metals, and they can also form molecular compounds with other non-metals.
  • The physical properties of halogens change down the group. Fluorine and chlorine are gases at room temperature, bromine is a liquid, and iodine and astatine are solids.
  • The density, boiling points and melting points of the halogens increase on moving down the group.
  • Halogens go from having very high electronegativities and electron affinities at the top of the group to much lower ones at the bottom of the group.
  • Halogens can exhibit multiple oxidation states, although they most commonly exhibit an oxidation state of -1 when forming ions.
  • They form diatomic molecules (meaning two atoms bond to form a molecule) in their natural state.
  • Fluorine is a pale yellow gas, chlorine is a green-yellow gas, bromine is a red-brown liquid, and iodine is a grey solid which produces a purple vapour when heated.
  • Here are a few examples of real-world applications of halogens: chlorine is used in water treatment to kill bacteria; iodine is used as an antiseptic; and fluorine is added to toothpaste to prevent tooth decay.

Remember, this information about Group 7 halogens can support learners’ knowledge of reactivity in other groups, patterns within the Periodic Table, and how these elements interact with their environment.