Polymers

Polymers

  • Polymers are large molecules made up of repeating subunits called monomers.
  • There are a wide variety of polymers, each with different properties and uses, ranging from common substances like plastics to biological polymers like proteins and DNA.
  • Factors that affect the properties of a polymer include the nature of the monomers used, the length of the polymer chain, and the degree of branching or cross-linking between chains.
  • Many polymers, such as polyethylene and polypropylene, are made from simple hydrocarbon monomers, but others, including proteins, are made from complex monomers with specific functional groups.

Polymerization

  • The process of forming a polymer from monomers is known as polymerisation.
  • There are two main types of polymerisation: addition polymerisation and condensation polymerisation.
  • In addition polymerisation, the monomers simply add together to form the polymer, with no other products.
  • In condensation polymerisation, two different types of monomers react together, with the elimination of a small molecule, usually water.

Properties and Uses of Polymers

  • The physical properties of polymers and their behaviour under different conditions can be altered by changing the nature of the monomers used and the conditions of polymerisation.
  • For example, the degree of crystallinity in a polymer, which is associated with rigidity and high melting point, can be increased by slowing down the rate of cooling after the polymer is formed.
  • Polymers can be broadly divided into thermosetting and thermoplastic types.
  • Thermosetting polymers are cross-linked and cannot be remoulded on heating, while thermoplastic polymers can be remoulded multiple times upon heating.
  • Polymers have a wide range of applications, from packaging materials to insulation wires, medical appliances, clothing and more.