Fundamentals of organic chemistry

Fundamentals of organic chemistry

Introduction to Organic Chemistry

  • Organic chemistry is the study of carbon-containing compounds, including hydrocarbons and their derivatives.
  • Organic compounds can contain other elements, such as hydrogen, nitrogen, oxygen, halogens, phosphorus, silicon, and sulphur.
  • The carbon atom is unique in its ability to form strong covalent bonds with other carbon atoms, creating long chains or rings.
  • Carbon atoms can form four covalent bonds, allowing for a versatility and complexity of structures.

Hydrocarbons

  • Hydrocarbons are organic compounds that contain only carbon and hydrogen.
  • They can be divided into two categories: alkanes and alkenes.
  • Alkanes are saturated hydrocarbons, which means they only contain single bonds. Their general formula is CnH2n+2.
  • Alkenes are unsaturated hydrocarbons, containing one or more carbon-carbon double bonds. Their general formula is CnH2n.

Homologous Series

  • A homologous series is a series of organic compounds with similar structures and properties, where each member differs by a CH2 unit.
  • Members of the same homologous series show trends or gradations in physical properties.
  • Every member of a homologous series can be represented by a general formula.

Functional Groups

  • A functional group is an atom or a group of atoms that determines the chemical properties of a compound.
  • Common functional groups include alcohols (OH), aldehydes (CHO), ketones (C=O), carboxylic acids (COOH), and amines (NH2).
  • Compounds containing the same functional group are often similar in their chemical reactions.

Nomenclature of Organic Compounds

  • The IUPAC nomenclature of organic compounds is systematic and depends on the number of carbon atoms, type of bonds, and functional groups present.
  • For example, the prefixes ‘meth-‘, ‘eth-‘, ‘prop-‘, and ‘but-‘ are used for compounds with one, two, three, and four carbon atoms, respectively.

Isomers

  • Isomers are compounds with the same molecular formula but different structural formulas.
  • Isomers can have very different chemical and physical properties, despite having the same molecular formula.
  • There are two types of isomers: structural isomers, where the atoms are joined in a different order, and stereoisomers, which have the same structural formula but a different arrangement of atoms in space.

Reactions of Organic Compounds

  • Organic compounds can undergo several types of reactions, including substitution reactions, addition reactions, elimination reactions and oxidation reactions.
  • Alkanes generally undergo substitution reactions, while alkenes undergo addition reactions.