Hydrocarbons and Crude Oil

Hydrocarbons

A hydrocarbon is a molecule that is made out of only hydrogen atoms and carbon atoms. The carbon atoms form a chain and the hydrogen atoms are bonded to the carbon chain.

These are all examples of hydrocarbons.

These are all saturated hydrocarbons. This means that there are no double bonds. Hydrocarbons with only single bonds are called alkanes.

When a hydrocarbon is unsaturated, it has some double bonds. These are called an alkenes.

Properties of hydrocarbons

1. The shorter the chain, the more runny it is (less viscous).
2. The shorter the chain, the lower the boiling and melting points.
3. The shorter the chain, the more flammable the hydrocarbon is.

Combustion

Combustion happens when something reacts with oxygen. This is done by burning it in air.

The general equation for complete combustion is:

When incomplete combustion happens, it means that there wasn’t enough oxygen available to react. Carbon or carbon monoxide form instead of carbon dioxide. Carbon Monoxide is a toxic gas.

Crude Oil

Crude oil is just a mixture of lots of different sized chains of hydrocarbons! It is found under ground. Crude oil is the remains of dead plants and animals from millions of years ago. The pressure from the earth squished them into a sludge called crude oil. We burn crude oil as fuel for energy production. This is bad for the atmosphere since it releases carbon dioxide (greenhouse gas).

Fractional Distillation

Crude oil is not very useful as it is, we need to separate the different hydrocarbon chains in order for them to be useful. Luckily, the boiling point depends on chain length!

To separate the the different hydrocarbon chain lengths, we place the crude oil into a fractionating column. The bottom of the column is hottest and the top is cool.

1. The crude oil is pumped into the bottom of the column, where it is so hot that the majority of the hydrocarbons turn from a liquid to gas.
2. The chains that are too long are drained out (this is the residue that we call bitumen).
3. The gaseous hydrocarbon chains travel up the column (since gas rises).
4. When a chain comes to a bit in the column where it is cool enough for it to turn back into a liquid, it does so. The liquid is collected in troughs and taken out of the chamber.
5. The Smallest chains condense nearer to the top (where it is cooler) and the longer chains condense closer to the bottom (where it is cooler).

You will need to know what the different chain lengths are called (i.e petrol) and what they are used for.

Cracking Crude Oil

Short chain hydrocarbons are more flammable and make very good (and useful) fuels. The longer chains are not as useful. For this reason, we tend to break up the longer chains into lots of smaller chains! This can be done through cracking. This is done by heating up the crude oil!

A catalyst can be used to help this decomposition, this catalyst is usually aluminium oxide.

Cracking produces alkanes and alkenes (hydrocarbons with double carbon bonds).